You may need to download version 2.0 now from the Chrome Web Store. However, carbonate of lithium, when heated, decomposes to form lithium oxide. The correct option is: (a) BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Explanation: In all cases, for a particular set of e.g. * Thermal stability of group-1 and group-2 carbonates (also of bicarbonates) increases down the group as the polarizing power of the metal ion decreases. Upon heating, carbonates decompose into oxide and carbon dioxide; The thermal stability of group-1 and group-2 carbonates increase down the group. so, the correct order of thermal stability of given carbonates is: BeCO 3 < MgCO 3 < CaCO 3 < K 2 CO 3 Be, Mg and Ca present in second group and K present in the first group. Still have questions? To test what you've learned from this lesson- Answer to question 23 the calcium ion has a larger charge (2+) thatn the potassium ion (1+). 1. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. Down the group, the carbonates require more heating to decompose. Thermal stability of carbonates increases in a group as we move from top to bottom and decreases in a period as we move from left to right. The electron cloud of anion is distorted to a lesser extent. Completing the CAPTCHA proves you are a human and gives you temporary access to the web property. Group 2 Oxides & Hydroxides w/ Water & Dilute Acid (6:58) Group 2 Salts - Solubility & Tests (7:27) Thermal Stability of Group 1/2 Carbonates (8:19) Correct order of stability of group 2a metal carbonates is 1 See answer mohitrathimr4440 is waiting for your help. For example, alkali metal salts such as sulptlates, carbonates, nitrates and perchlorates possess greater stability than the corresponding salts of less reactive metals, or the corresponding free acids. Hence, Thermal stability order : $\ce{MgCO3 CaCO3 SrCO3 BaCO3}$ The rest of group 1 follow the same pattern. The larger compounds further down require more heat than the lighter compounds in order to decompose. From Li to Cs, due to larger ion size, hydration enthalpy decreases. If ice is less dense than liquid water, shouldn’t it behave as a gas? All these carbonates decompose on heating to give CO 2 and metal oxide. THE thermal stabilities of salts containing the same anion are well known to differ for different cations. Performance & security by Cloudflare, Please complete the security check to access. All the Group 2 carbonates and their resulting oxides exist as white solids. 3H2O, evaluated by in situ laboratory parallel-beam X-ray powder diffraction: New constraints on CO2 sequestration within minerals, Journal of Hazardous Materials 178, no.1-3 1-3 (Jun 2010): 522–528. spontaneous combustion - how does it work? Thermal Stability is the decomposition of a compound on heating. Carbonates of metal: Thermal stabilityThe carbonates of alkali metals except lithium carbonate are stable to heat. Add your answer and earn points. • All these carbonates decompose on heating to give CO 2 and metal oxide. So, solubility should decrease from Li to Cs. Also, lithium carbonate is unstable due to the high polarising power of the lithium ion due to its small size (same explanation as for the Group 2 carbonates). All of these carbonates are white solids, and the oxides that are produced are also white solids. Thermal Stability. It means the stability increases from M g C O 3 to B a C O 3 . Zinc carbonate and sodium hydroxide? Group 1 or Group 2 compounds, the thermal stability increases down the group as the ionic radius of the cation increases, and its polarising power decreases. As we go down the group, the carbonates have to be heated more strongly before they will decompose. (substitute Na, K … Thermal stability of Alkaline earth metals carbonates increases down the group. All of these carbonates are white solids, and the oxides that are produced are also white solids. What is the  molar concentration of sodium nitrate .? Explanation: New questions in Chemistry. Also, does thermal stability increase or decrease as you go down group 1 (with explanation please)? At an elementary level, the relative thermal stability of the carbonates of the metals cannot easily be explained in terms of simple ideas of bonding in these compounds. Thermal Stability is the decomposition of a compound on heating. The decomposition temperatures again increase down the Group. How many grams of glucose would be formed in a reaction in which 23.576 grams of carbon dioxide were consumed? Generally increases down the group. Please enable Cookies and reload the page. Nature of carbonates and bicarbonates: Alkali metal carbonates and bicarbonate stability increases down the group. All the alkaline earth metals form carbonates (MCO 3). The Facts. The thermal stability; of these carbonates increases down the group, i.e., from Be to Ba, BeCO 3 < MgCO 3 < CaCO 3 < SrCO 3 < BaCO 3 BeCO 3 is unstable to the extent that it is stable only in atmosphere of CO 2. Thermal stability of group 2 carbonates experiment Group 1 and 2 metal hydroxides AQA C2 Acids, Bases & Salts Help Chemistry igcse 0620/33 may/june 2011 Are Group 2 oxides soluble in water? Join Yahoo Answers and get 100 points today. Calcium ion also has a smaller radius and so a higher charge density giving it a greater polarising power allowing it to distort the bonding From Li to Cs, thermal stability of carbonates increases. Decomposition becomes more difficult and thermal stability increases. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. Cloudflare Ray ID: 61032405aebff166 The carbonates become more thermally stable down the group. The carbonates of group-2 metals and that of lithium decompose on heating, forming an oxide and carbon dioxide . In group1,it is found that the thermal stability of hydroxides,carbonates,nitrates sulphates etc. Solution for group 1 elements with that of group 2 on the basis of the following:… * Due to same reason, carbonates of group-1 are more stable than those of group-2. All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. If "X" represents any one of the elements: All the carbonates in this Group undergo thermal decomposition to give the metal oxide and carbon dioxide gas. If "X" represents any one of the elements: 18. So thermal stability increases. So what is thermal stability? This decreases the charge density and the ability of the cation to polarize the anion. I cannot wrap my head around this. 3. It's how resistant a molecule is to decomposition at higher temperatures. The term "thermal decomposition" describes splitting up a compound by heating it. The quote from your text: So the stability that you are referring to is thermal stability.This is an important detail. By contrast, the least soluble Group 1 carbonate is lithium carbonate. I know stability increases as you go down group 2, please explain why in language a good A level student can understand. The carbonates of alkaline earth metals also decompose on heating to form oxide and carbon dioxide. All the carbonates in this group undergo thermal decomposition to the metal oxide and carbon dioxide gas. Both carbonates and nitrates of Group 2 elements become more thermally stable down the group. A simple relationship between the reactivity of the metal and the stability of its compounds, such as the carbonate here, will have to suffice. 6. Favourite answer Thermal stability increases down the group because the size of the cation (positive ion) increases, so the lattice energy of the carbonate … Thermal stability The carbonates of alkali metals are stable towards heat. Another way to prevent getting this page in the future is to use Privacy Pass. Stability of metal carbonates One common reaction of any metal carbonates is known as thermal decomposition. Going down group II, the ionic radii of cations increases. • The rest of the Group 1 carbonates do not decompose at laboratory temperatures, although at higher temperatures this becomes possible. Get answers by asking now. Magnesium carbonate (the most soluble one I have data for) is soluble to the extent of about 0.02 g per 100 g of water at room temperature. If you are at an office or shared network, you can ask the network administrator to run a scan across the network looking for misconfigured or infected devices. You will often find unusual properties for the first member of a group. I am a metal and placed above iron in the activity series. So the correct order of stability of carbonates of Group IIA is B a C O 3 > S r C O 3 > C a C O 3 > M g C O 3 . Is lithium carbonate are stable to heat of cations increases you from residue and odour carbonate lithium. This page in the activity series after decreasing the pressure of a group becomes possible complete... Decrease as you go down the group 1 carbonates do not decompose at laboratory temperatures, although at higher this... Version 2.0 now from the carbonate to the metal oxide and carbon dioxide ; the thermal stability the of. 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